1374017-36-3Relevant academic research and scientific papers
Efficient synthesis of phenylene-ethynylene rods and their use as rigid spacers in divalent inhibitors
Pertici, Francesca,Varga, Norbert,Van Duijn, Arnoud,Rey-Carrizo, Matias,Bernardi, Anna,Pieters, Roland J.
supporting information, p. 215 - 222 (2013/03/14)
The synthesis of phenylene-ethynylene rods and their use as rigid spacers is described. Alternation of a Sonogashira reaction and silyl group cleavage was used to obtain rigid spacers with even and odd numbers of phenylene units. Preliminary applications of these rods in divalent systems are shown. Inhibition studies with Pseudomonas Aeruginosa lectin LecA showed that the rigid spacer proved greatly beneficial for the inhibitory potency.
Synthesis and characterization of near-infrared emissive BODIPY-based conjugated polymers
Wu, Yuanzhao,Ma, Xiao,Jiao, Jiemin,Cheng, Yixiang,Zhu, Chengjian
supporting information; scheme or table, p. 778 - 782 (2012/07/27)
Three novel BODIPY-based conjugated polymers could be synthesized via palladium-catalyzed Sonogashira coupling reaction. Compared with BODIPY model derivatives, the polymers can emit in the range from deep-red to near-infrared region with emission spectral maxima at = 640-660 nm and exhibit moderate fluorescent quantum yield from 0.23 to 0.26. Density functional theory (DFT) calculations are performed on three polymers repeat units, and HOMO and LUMO energy levels of the conjugated polymers are estimated. Georg Thieme Verlag Stuttgart · New York.
Polymer-based colorimetric and "turn off" fluorescence sensor incorporating benzo[2,1,3]thiadiazole moiety for Hg2+ Detection
Ma, Xiao,Song, Fengyan,Wang, Lu,Cheng, Yixiang,Zhu, Chengjian
scheme or table, p. 517 - 522 (2012/04/23)
A conjugated polymer was synthesized by the polymerization of 4,7-dibromobenzo[2,1,3]thiadiazole (M-1) with tri{1,4-diethynyl-2,5-bis(2-(2- methoxyethoxy)-ethoxy)}-benzene (M-2) via Pd-catalyzed Sonogashira reaction. The polymer shows strong orange fluorescence. The responsive optical properties of the polymer on various metal ions were investigated through photoluminescence and UV-vis absorption measurements. The polymer displays highly sensitive and selective on-off Hg2+ fluorescence quenching property in tetrahydrofuran solution in comparison with the other cations including Mg 2+, Zn2+, Co2+, Ni2+, Cu 2+, Ag+, Cd2+, and Pb2+. More importantly, the fluorescent color of the polymer sensor disappears after addition of Hg2+, which could be easily detected by naked eyes. The results indicate that this kind of polymer sensor incorporating benzo[2,1,3]thiadiazole moiety as a ligand can be used as a novel colorimetric and fluorometric sensor for Hg2+ detection. 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 Polymer-based colorimetric and "turn off" fluorescence sensor can exhibit the most pronounced fluorescence response to Hg2+ detection without interference from other metal ions. Copyright
A highly selective and sensitive polymer-based fluorescence sensor for Hg2+-ion detection via click reaction
Wu, Yuanzhao,Dong, Yu,Li, Junfeng,Huang, Xiaobo,Cheng, Yixiang,Zhu, Chengjian
supporting information; experimental part, p. 2725 - 2729 (2012/06/15)
Mercury rising: A Highly Selective and sensitive polymer-based fluorescence sensor synthesized using click reactions affords the most-pronounced fluorescence response to Hg2+ ions.
Chemosensory performance of molecularly imprinted fluorescent conjugated polymer materials
Li, Jiahui,Kendig, Claire E.,Nesterov, Evgueni E.
, p. 15911 - 15918 (2008/09/21)
Fluorescent conjugated polymers are an attractive basis for the design of low detection limit sensing devices owing to their intrinsic signal amplification capability. A simple and universal method to rationally control or fine-tune the chemodetection sel
