1374126-27-8

Basic information

• Product Name: [4-(CH₃)2CHC₆H₄C(O)CHPPh₃]
• Synonyms: [4-(CH₃)2CHC₆H₄C(O)CHPPh₃]
• CAS NO: 1374126-27-8
• Molecular Weight: 422.507
• Mol File: 1374126-27-8.mol

Chemical Properties

• CAS DataBase Reference: [4-(CH₃)2CHC₆H₄C(O)CHPPh₃](CAS DataBase Reference)
• NIST Chemistry Reference: [4-(CH₃)2CHC₆H₄C(O)CHPPh₃](1374126-27-8)
• EPA Substance Registry System: [4-(CH₃)2CHC₆H₄C(O)CHPPh₃](1374126-27-8)

Safety Data

• Hazardous Substances Data: 1374126-27-8(Hazardous Substances Data)

Upstream product

• 645-13-6 4-isopropylacetophenone 
• 51012-62-5 α-bromomethyl 4-isopropylphenyl ketone 
• 603-35-0 triphenylphosphine 

Downstream Products

• 1374126-24-5 (Ag(((CH₃)2CH)C₆H₄C(O)CHP(C₆H₅)3)2)⁽¹⁺⁾*NO₃^(1-)=(Ag(((CH₃)2CH)C₆H₄C(O)CHP(C₆H₅)3)2)(NO₃) 

Relevant articles and documents

Organocatalytic Enantioselective Selenosulfonylation of a C-C Double Bond to Form Two Stereogenic Centers in an Aqueous Medium

Organocatalytic selenosulfonylation of the C-C double bond of α,β-unsaturated ketones to construct two contiguous stereogenic centers in an aqueous medium was described. A series of α-selenyl and β-sulfonyl ketones with various functional groups were synthesized in good yields and enantioselectivities with saturated NaCl solution as the solvent. In addition, this protocol had been successfully scaled up to a decagram scale via a simple workup procedure.

Structural, theoretical and multinuclear NMR study of mercury(II) and silver(I) complexes with two new ambidentate phosphorus ylides

Reactions of new α-ketostabilized phosphorus ylides of the type Ph3P = CHC(O)R (R = 2,4-dichlorophenyl (L1) and 4-isopropylphenyl (L2)) with AgNO3and Hg(NO 3)2.H2O, using methanol as a solvent, are reported. The crystal structures of L2 and [Ag(L2) 2(NO3)] (2) have been determined. Characterization of the obtained compounds was also performed by elemental analysis, IR, 1H, 31P and 13C NMR. Theoretical studies were carried out on the silver(I) complexes. It was shown that the nitrate ion shows a bonding interaction with the silver ion.