1374215-49-2

Upstream product

• 1374215-42-5 (S)-3-hydroxycyclohexa-1,5-dien-1-yl trifluoromethanesulfonate 
• 1374215-43-6 (1R,4S,6R)-4-hydroxy-7-oxabicyclo[4.1.0]hept-2-en-2-yl trifluoromethanesulfonate 
• 1374215-45-8 (1R,4S,6R)-4-((tert-butyldimethylsilyl)oxy)-7-oxabicyclo[4.1.0]hept-2-en-2-yl-trifluoromethanesulfonate 
• 63028-10-4 cyclohexa-2,4-dienyl trifluoromethanesulfonate 
• 224630-64-2 (1R,6R)-7-oxabicyclo[4.1.0]hept-2-en-2-yl trifluoromethanesulfonate 

Downstream Products

• 1374215-47-0 (1R,2S,5S)-2-acetamido-5-((tert-butyldimethylsilyl)oxy)-3-(((trifluoromethyl)sulfonyl)oxy)cyclohex-3-en-1-yl acetate 
• 1374215-48-1 (1R,2R,5S)-2-acetamido-3-(benzo[d][1,3]dioxol-5-yl)-5-((tertbutyldimethylsilyl)oxy)cyclohex-3-en-1-yl acetate 
• 1374215-46-9 (1R,2S,5S)-2-azido-5-((tert-butyldimethylsilyl)oxy)-3-(((trifluoromethyl)sulfonyl)oxy)cyclohex-3-en-1-yl acetate 

Relevant academic research and scientific papers

Jacobsen protocols for large-scale epoxidation of cyclic dienyl sulfones: Application to the (+)-pretazettine core

A Jacobsen epoxidation protocol using H2O2 as oxidant was designed for the large-scale preparation of various epoxy vinyl sulfones. A number of cocatalysts were screened, and pH control led to increased reaction rate, higher turnover