137423-20-2Relevant academic research and scientific papers
Total Synthesis of (+)-Lycoricidine and Its 2-Epimer from D-Glucose
Chida, Noritaka,Ohtsuka, Masami,Ogawa, Seiichiro
, p. 4441 - 4447 (2007/10/02)
Stereoselective total synthesis of antimitotic alkaloid (+)-lycoricidine (1) and its 2-epimer (30) was accomplished starting from D-glucose.The key steps in this synthesis are (i) a catalytic version of the Ferrier rearrangement for the preparation of the
Stereoselective Total Synthesis of (+)-Lycoricidine
Chida, Noritaka,Ohtsuka, Masami,Ogawa, Seiichiro
, p. 4525 - 4528 (2007/10/02)
The stereoselective total synthesis of the title compound starting from D-glucose is described.The key steps in this synthesis are Ferrier rearrangement to construct the optically active cyclohexenone (C-ring), and Pd-catalyzed intramolecular Heck reactio
