1374451-70-3Relevant academic research and scientific papers
Extrusion of CO from aryl ketones: Rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group
Lei, Zhi-Quan,Li, Hu,Li, Yang,Zhang, Xi-Sha,Chen, Kang,Wang, Xin,Sun, Jian,Shi, Zhang-Jie
, p. 2690 - 2694 (2012)
Snipping tool: The rhodium(I)-catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields (see scheme). A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for C-C bond activation. Copyright
