1374458-70-4

Upstream product

• 1374458-69-1 ethyl (E,4R,5R,6R,7R)-6-[(tert-butyldimethylsilyl)oxy]-8-[(tert-butyldiphenylsilyl)oxy]-4-methoxy-2,5,7-trimethyl-2-octenoate 
• 1374458-68-0 tert-butyl{[(1R,2R,3R,4E)-1-{(1R)-2-[(tert-butyldiphenylsilyl)oxy]-1-methylethyl}-3-methoxy-2-methyl-5-phenyl-4-pentenyl]oxy}dimethylsilane 
• 1374458-67-9 (2R,3R,4S,5R,6E)-1-[(tert-butyldiphenylsilyl)oxy]-5-methoxy-2,4-dimethyl-7-phenyl-6-hepten-3-ol 
• 1374458-66-8 (2R,3R,4S,5R,6E)-5-methoxy-2,4-dimethyl-7-phenyl-6-heptene-1,3-diol 
• 1374458-61-3 {(2S,3S)-3-[(1R,2R,3E)-2-methoxy-1-methyl-4-phenyl-3-butenyl]-oxiran-2-yl}methanol 
• 1374458-65-7 {(2S,3S)-3-[(1R,2R,3E)-2-methoxy-1-methyl-4-phenyl-3-butenyl]-oxiran-2-yl}methanol 
• 1374458-64-6 ethyl (2E,4S,5R,6E)-5-methoxy-4-methyl-7-phenyl-2,6-heptadienoate 
• 1374458-63-5 ethyl (2E,4S,5R,6E)-5-hydroxy-4-methyl-7-phenyl-2,6-heptadienoate 

Relevant academic research and scientific papers

Towards the synthesis of (-)-callipeltoside A: Stereoselective synthesis of the C1-C14 macrolactone core

A highly stereoselective synthesis of the C1-C14 macrolactone core of the cytotoxic macrolide (-)-callipeltoside A has been achieved by utilizing an anti-selective aldol reaction and Wittig olefination to introduce an (E)-trisubstituted alkene, chemoselec