1374510-60-7Relevant academic research and scientific papers
Benzotriazole-bridged sensitizers containing a furan moiety for dye-sensitized solar cells with high open-circuit voltage performance
Mao, Jiangyi,Guo, Fuling,Ying, Weijiang,Wu, Wenjun,Li, Jing,Hua, Jianli
, p. 982 - 991 (2012)
Two new benzotriazole-bridged sensitizers are designed and synthesized (BTA-I and BTA-II) containing a furan moiety for dye-sensitized solar cells (DSSCs). Two corresponding dyes (BTA-III and BTA-IV) with a thiophene spacer were also synthesized for comparison. All of these dyes performed as sensitizers for DSSCs, and the photovoltaic performance data of these benzotriazole-bridged dyes showed a high open-circuit voltage (Voc: 804-834 mV). Among the four dyes, DSSCs based on BTA-II, with a furan moiety and branched alkyl chain, showed the highest Voc (834 mV), a photocurrent density (J sc) of 12.64 mA cm-2, and a fill factor (FF) of 0.64, corresponding to an overall conversion efficiency (η) of 6.72 %. Most importantly, long-term stability of the BTA-I-IV-based DSSCs with ionic-liquid electrolytes under 1000 h light-soaking was demonstrated, and BTA-II exhibited better photovoltaic performance of up to 5.06 % power conversion efficiency.
