1374569-27-3

Upstream product

• 56506-08-2 (Z)-oct-4-ene-1,8-diol 
• 1374569-28-4 C₉H₁₆Br₂O₂ 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 1374569-29-5 ((((1R,2S)-3,3-dibromocyclopropane-1,2-diyl)bis(propane-3,1-diyl))bis(oxy))dibenzene 

Relevant academic research and scientific papers

Force-reactivity property of a single monomer is sufficient to predict the micromechanical behavior of its polymer

We demonstrate an accurate prediction of the micromechanical behavior of a single chain of cyclopropanated polybutadiene, which is governed by rapid isomerization of the cyclopropane moieties at ～1.2 nN, from the force-rate correlation of this reaction measured in a small series of increasingly strained macrocycles. The data demonstrate that a single physical quantity, force, uniquely defines the dynamics across length scales from >100 to 1 nm and that strain imposed through molecular design and that imposed by micromanipulation techniques have equivalent effects on the kinetics of a chemical reaction. This represents a new method of screening potential monomers for applications in stress-responsive materials that could also facilitate atomistic interpretations of single-molecule force experiments.