1374646-02-2Relevant academic research and scientific papers
Menthane-Based Chloride-Bridged η3-Bis-π-Allylpalladium Chloride Dimers: Catalytic Asymmetric Allylation of Imines
Jha, Amit K.,Fernandes, Rodney A.
, p. 2857 - 2863 (2019)
Menthane-based η3-bis-π-allylpalladium chloride dimer complexes have been prepared for the first time. They exist as dimeric η3-bis-π-allylpalladium with four chloride bridges. The complexes catalyze the asymmetric allylation of vari
Development of the first menthane-based chiral bis(π-allylpalladium) catalysis: Asymmetric allylation of imines
Fernandes, Rodney A.,Chaudhari, Dipali A.
experimental part, p. 1945 - 1952 (2012/05/20)
A new ethylidene menthane-based chiral π-allylpalladium complex catalyzes the asymmetric allylation of various imines with allyltributylstannane and 1 equiv. of water to give chiral homoallylamines in good yields and enantioselectivities. The reaction was carried out essentially under neutral conditions and displayed a good transfer of chiral information from the menthane skeleton through the formation of a bis(π-allylpalladium) species. This is the first example of menthane-based chiral bis(π-allylpalladium) catalysis. A menthane-based chiral π-allylpalladium-catalyzed asymmetric allylation of various imines has been developed giving chiral homoallylamines in good yields and enantioselectivities. The reaction displays a good transfer of chiral information from the menthane skeleton through the formation of a bis(π-allylpalladium) complex. Copyright
