1374751-54-8

Basic information

• Product Name: 1,3,5-tri(3′-mesitylbiphen-2-yl)benzene
• Synonyms: 1,3,5-tri(3′-mesitylbiphen-2-yl)benzene
• CAS NO: 1374751-54-8
• Molecular Weight: 889.235
• Mol File: 1374751-54-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,3,5-tri(3′-mesitylbiphen-2-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-tri(3′-mesitylbiphen-2-yl)benzene(1374751-54-8)
• EPA Substance Registry System: 1,3,5-tri(3′-mesitylbiphen-2-yl)benzene(1374751-54-8)

Safety Data

• Hazardous Substances Data: 1374751-54-8(Hazardous Substances Data)

Upstream product

• 380626-56-2 1,3,5-tris(2′-bromophenyl)benzene 
• 1374751-53-7 1,3,5-tri(3′-chlorobiphen-2-yl)benzene 
• 2633-66-1 2-mesitylmagnesium bromide 

Downstream Products

• 1374751-55-9 5,11,17-trimesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,8,14-triyltris(trifluoromethanesulfonate) 

Relevant articles and documents

A Three-Dimensional Capsule-like Carbon Nanocage as a Segment Model of Capped Zigzag [12,0] Carbon Nanotubes: Synthesis, Characterization, and Complexation with C70

Herein we report the synthesis and photophysical and supramolecular properties of a novel three-dimensional capsule-like hexa-peri-hexabenzocoronene (HBC)-containing carbon nanocage, tripodal-[2]HBC, which is the first synthetic model of capped zigzag [12,0] carbon nanotubes (CNTs). Tripodal-[2]HBC was synthesized by the palladium-catalyzed coupling of triboryl hexabenzocoronene and L-shaped cyclohexane units, followed by nickel-mediated C?Br/C?Br coupling and subsequent aromatization of the cyclohexane moieties. The physical properties of tripodal-[2]HBC and its supramolecular host–guest interaction with C70 were further studied by UV/Vis and fluorescence spectroscopy. Theoretical calculations revealed that the strain energy of tripodal-[2]HBC was as high as 55.2 kcal mol?1.