1374869-48-3Relevant academic research and scientific papers
Iodine(III)-promoted intermolecular diamination of alkenes
Souto, Jose A.,Gonzalez, Yolanda,Iglesias, Alvaro,Zian, Debora,Lishchynskyi, Anton,Muniz, Kilian
supporting information; experimental part, p. 1103 - 1111 (2012/07/17)
A rapid and productive vicinal diamination of alkenes takes place in the presence of a hypervalent iodine(III) reagent and bissulfonimides as nitrogen sources. A total of more than 60 examples are presented. The reaction is characterized by its robustness and its wide substrate scope: it proceeds selectively with both terminal and internal alkenes and tolerates a range of functional groups.
Enantioselective metal-free diamination of styrenes
Roeben, Caren,Souto, Jose A.,Gonzalez, Yolanda,Lishchynskyi, Anton,Muniz, Kilian
supporting information; experimental part, p. 9478 - 9482 (2011/11/06)
Metal-free and asymmetric: The first enantioselective diamination of styrenes simply requires a chiral hypervalent iodine(III) reagent as an oxidant and bismesylimide as a nitrogen source (see scheme, Ms=methanesulfonyl). The reaction proceeds under mild conditions and with high enantiomeric excess.
