1374870-87-7

Basic information

• Product Name: (2S,3E,5Z)-6-((2R,4aR,8R,8aR)-8-[(tert-butyldimethylsilyl)oxy]-2-phenyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-6-yl)hepta-3,5-diene-1,2-diol
• Synonyms: (2S,3E,5Z)-6-((2R,4aR,8R,8aR)-8-[(tert-butyldimethylsilyl)oxy]-2-phenyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-6-yl)hepta-3,5-diene-1,2-diol
• CAS NO: 1374870-87-7
• Molecular Weight: 474.67
• Mol File: 1374870-87-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3E,5Z)-6-((2R,4aR,8R,8aR)-8-[(tert-butyldimethylsilyl)oxy]-2-phenyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-6-yl)hepta-3,5-diene-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3E,5Z)-6-((2R,4aR,8R,8aR)-8-[(tert-butyldimethylsilyl)oxy]-2-phenyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-6-yl)hepta-3,5-diene-1,2-diol(1374870-87-7)
• EPA Substance Registry System: (2S,3E,5Z)-6-((2R,4aR,8R,8aR)-8-[(tert-butyldimethylsilyl)oxy]-2-phenyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-6-yl)hepta-3,5-diene-1,2-diol(1374870-87-7)

Safety Data

• Hazardous Substances Data: 1374870-87-7(Hazardous Substances Data)

Upstream product

• 917-54-4 methyllithium 
• 142393-21-3 1,5-anhydro-4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-2-deoxy-1-tributylstannyl-D-arabino-hex-1-enitol 

Relevant articles and documents

Copper(I)-mediated 1,2-metallate rearrangements of 1-metallated glycals

1,2-Metallate rearrangements involving reaction of 1-metallated glycals with organolithium reagents under copper(I) mediation give alkenylpolyol chains in 45-91% yield (19 examples). The reaction was applied to a formal synthesis of KRN7000 as well as a synthesis of a 5,6-ceramide derivative. Georg Thieme Verlag Stuttgart · New York.