1374880-16-6

Basic information

• Product Name: tert-butyl [(1R,2S)-1-cyclohexyl-2-nitropent-4-en-1-yl]carbamate
• CAS NO: 1374880-16-6
• Molecular Weight: 312.409
• Mol File: 1374880-16-6.mol

Chemical Properties

• CAS DataBase Reference: tert-butyl [(1R,2S)-1-cyclohexyl-2-nitropent-4-en-1-yl]carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl [(1R,2S)-1-cyclohexyl-2-nitropent-4-en-1-yl]carbamate(1374880-16-6)
• EPA Substance Registry System: tert-butyl [(1R,2S)-1-cyclohexyl-2-nitropent-4-en-1-yl]carbamate(1374880-16-6)

Safety Data

• Hazardous Substances Data: 1374880-16-6(Hazardous Substances Data)

Upstream product

• 2043-61-0 cyclohexanecarbaldehyde 
• 32349-29-4 4-nitrobut-1-ene 
• 253426-70-9 tert-butyl cyclohexyl(phenylsulfonyl)methylcarbamate 
• 4248-19-5 tert-butyl carbazate 

Relevant articles and documents

A new family of cinchona-derived bifunctional asymmetric phase-transfer catalysts: Application to the enantio- and diastereoselective nitro-Mannich reaction of amidosulfones

A new family of bifunctional H-bond donor phase-transfer catalysts derived from cinchona alkaloids has been developed and evaluated in the enantio- and diastereoselective nitro-Mannich reaction of in situ generated N-Boc-protected imines of aliphatic, aromatic, and heteroaromatic aldehydes. Under optimal conditions, good reactivity and high diastereoselectivities (up to 24:1 dr) and enantioselectivities (up to 95% ee) were obtained using a 9-amino-9- deoxyepiquinidine-derived phase-transfer catalyst possessing a 3,5-bis(trifluoromethyl)phenylurea H-bond donor group at the 9-position.