137495-34-2Relevant academic research and scientific papers
Structural Analysis of cis-Bicyclic Ketones by X-ray Crystallography. Impact of the Observed Conformational Crossover on ?-Facially Diastereoselective Nucleophilic Additions to This Class of Ketones and on the Stereochemical Course of Electrophilic
Paquette, Leo A.,Underiner, Ted L.,Gallucci, Judith C.
, p. 86 - 96 (2007/10/02)
X-ray crystallographic studies clearly show that cis-bicyclic ketones 1 having n equal to 7 or less are conformationally predisposed such that the rigid chair cyclohexanone ring projects the polymethylene chaine diaxially.In contrast, an increase i
