1375536-69-8

Basic information

• Product Name: (E)-2-(4-(4-methoxyphenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Synonyms: (E)-2-(4-(4-methoxyphenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 1375536-69-8
• Molecular Weight: 288.195
• Mol File: 1375536-69-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-2-(4-(4-methoxyphenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(4-(4-methoxyphenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1375536-69-8)
• EPA Substance Registry System: (E)-2-(4-(4-methoxyphenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1375536-69-8)

Safety Data

• Hazardous Substances Data: 1375536-69-8(Hazardous Substances Data)

Upstream product

• 32507-39-4 (E)-1-(buta-1,3-diene-1-yl)-4-methoxybenzene 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 140-67-0 Estragole 
• 78782-17-9 4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane 
• 4180-23-8 E-1-(4'-methoxyphenyl)prop-1-ene 
• 90841-43-3 (E)-4-methoxycinnamyl bromide 

Relevant articles and documents

Silver-Catalyzed anti-Markovnikov Hydroboration of C-C Multiple Bonds

A simple silver salt (AgOAc)-catalyzed anti-Markovnikov-selective hydroboration of alkenes, 1,3-dienes, and alkynes with pinacolborane (HBpin) has been described. This strategy provides an efficient and practical method to access various alkyl-, allyl-, a

Cross coupling between sp3-carbon and sp3-carbon using a diborylmethane derivative at room temperature

A novel example of the Suzuki-Miyaura cross-coupling reaction between sp3-carbon and sp3-carbon is described. The reaction of a diborylmethane derivative with allyl halides or benzyl halides proceeded efficiently in the presence of appropriate Pd-catalysts at room temperature. The present approaches provide functionalized homoallylboronates and alkylboronates with excellent regio- and chemoselectivities.