1375536-79-0Relevant academic research and scientific papers
Cross coupling between sp3-carbon and sp3-carbon using a diborylmethane derivative at room temperature
Endo, Kohei,Ohkubo, Takahiro,Ishioka, Takafumi,Shibata, Takanori
, p. 4826 - 4831 (2012)
A novel example of the Suzuki-Miyaura cross-coupling reaction between sp3-carbon and sp3-carbon is described. The reaction of a diborylmethane derivative with allyl halides or benzyl halides proceeded efficiently in the presence of appropriate Pd-catalysts at room temperature. The present approaches provide functionalized homoallylboronates and alkylboronates with excellent regio- and chemoselectivities.
