13756-98-4

Upstream product

• 87787-09-5 6-hydroxymethyl-6-methyl-1,4-dioxaspiro<4.5>decane 
• 130735-25-0 methyl 3-methoxymethoxymethyl-3-methyl-2-oxocyclohexanecarboxylate 
• 130735-26-1 methyl 3-methoxymethoxymethyl-1,3-dimethyl-2-oxocyclohexanecarboxylate 
• 130735-17-0 2-Methoxymethoxymethyl-2-methylcyclohexanone 
• 130735-16-9 2-Methoxymethoxymethyl-2-methylcyclohexanone Ethylene Acetal 
• 66088-37-7 ethyl 1-methyl-2-oxocyclohexancarboxylate 
• 13839-77-5 Ethyl 6-methyl-1,4-dioxaspiro[4.5]decane-6-carboxylate 
• 130735-18-1 2-Methoxymethoxymethyl-2,6-dimethylcyclohexanone 
• 2816-57-1 2,6-dimethylcyclohexanone 
• 50-00-0 formaldehyd 

Downstream Products

• 107208-15-1 (+/-)-2,6-dimethyl-2-tetrahydropyranyl-oxymethyl-1-cyclohexanone 
• 130735-22-7 1,3-Dimethylcyclohex-2-ene-1,2-dicarbaldehyde 1-Ethylene Acetal 
• 130735-21-6 1,3-Dimethyl-2-oxocyclohexanecarbaldehyde Ethylene Acetal 
• 130735-23-8 1,3-Dimethylcyclohex-2-ene-1,2-dicarbaldehyde 
• 107208-16-2 2,6-Dimethyl-1-[3-(tetrahydro-pyran-2-yloxy)-but-1-ynyl]-2-(tetrahydro-pyran-2-yloxymethyl)-cyclohexanol 
• 107208-18-4 (+/-)-3-(6'-acetoxymethyl-1'-hydroxy-2',6'-dimethylcyclohexyl)-1-methyl-2-propynyl acetate 
• 107208-19-5 (+/-)-3-(6'-acetoxymethyl-2',6'-dimethyl-1'-cyclohexen-1'-yl)-1-methyl-2-propynyl acetate 
• 107208-22-0 (+/-)-4-(6'-acetoxymethyl-2',6'-dimethyl-1'-cyclohexen-1'-yl)-3-buten-2-one 
• 107208-17-3 (+/-)-4-(1'-hydroxy-2'-hydroxymethyl-2',6'-dimethylcyclohexyl)-but-3-yn-2-ol 
• 107208-21-9 (E)-4-(6-Hydroxymethyl-2,6-dimethyl-cyclohex-1-enyl)-but-3-en-2-one 
• 155638-29-2 (+/-)-4-(1'-hydroxy-2'-methoxymethyl-2',6'-dimethylcyclohexyl)-but-3-yn-2-ol-tetrahydropyranyl ether 
• 155638-32-7 (+/-)-3-(2'-methoxymethyl-2',6'-dimethyl-1'-cyclohexene-1'-yl)-1-methyl-2-propynyl acetate 
• 155638-31-6 (+/-)-3-(1'-hydroxy-6'-methoxymethyl-2',6'-dimethylcyclohexyl)-1-methyl-2-propynyl acetate 
• 155638-30-5 (+/-)-4-(1'-hydroxy-2'-methoxymethyl-2',6'-dimethylcyclohexyl)-but-3-yn-2-ol 

Relevant academic research and scientific papers

8'- and 9'-Methoxyabscisic Acids as Antimetabolic Analogs of Abscisic Acid

8'- and 9'-Methoxyabscisic acids (methoxy-ABAs) were synthesized as antimetabolic analogs of abscisic acid (ABA).The racemic mixtures were resolved by HPLC. (+)-8'-Methoxy-ABA inhibited the elongation of rice seedling four times more strongly than (+)-ABA did, and (+)-9'-methoxy-ABA inhibited the germination of lettuce seeds and the induction of α-amylase by gibberellin A3 in barley seeds seven and two times more strongly, respectively.These methoxy-ABAs are the first analogs reported to have higher activity than ABA. (+)-8'- and (+)-9'-Methoxy-ABAs were less active in causing stomatal closure than (+)-ABA.These biological activities and 1H-NMR analysis suggest that the activity of methoxy-ABAs involved delayed metabolism, as was expected.The activity of (-)-isomers of ABA and methoxy-ABAs was also tested.

Total Synthesis of (+)-Perrottetianal A

The total synthesis of (+)-perrottetianal A, one of the sacculatane-type diterpenes isolated from liverworts, has been achieved starting from an optically active Wieland-Miescher ketone analogue.The ethylene glycol monoacetal of the starting material was