137568-92-4Relevant academic research and scientific papers
Regiocontrol in Pd(0)-Mediated Couplings of a Bis(enol triflate) with Alkynes - Stereoselective Syntheses of Monocyclic Dienediynes Related to the Neocarzinostatin Chromophore
Scheuplein, Stefan W.,Harms, Klaus,Brueckner, Reinhard,Suffert, Jean
, p. 271 - 278 (2007/10/02)
The stereoselctive synthesis of (Z)-dienediynes 2 related to the neocarzinostatin chromophore 1 is described. (Z)-Bis(enol triflate) 3, accessible stereoselctively from 2-formylcyclopentanone in 2 steps, serves as the key intermediate.It is subjected to c
