137569-56-3Relevant academic research and scientific papers
Synthesis of a Novel Optically Active C2-Symmetric 2,2'-Bipyridine
Bolm, Carsten,Ewald, Martina,Zehnder, Margareta,Neuburger, Markus A.
, p. 453 - 458 (2007/10/02)
Optically active 2,2'-bipyridine (S,S)-1 was synthesized by radical cyclization and a nickel(0)-mediated coupling of enantiomerically pure bromopyridine (S)-8.Palladium, copper, and cobalt complexes of 1 were prepared.The solid-state structures of meso-1 and 11 were determined by X-ray crystal structure analysis. Key Words: 2,2'-Bipyridine / Chiral ligand / Palladium complexes / Copper complexes / Cobalt complexes
