137601-57-1

Basic information

• Product Name: Benzenamine, 4-(4,5,6,7-tetrahydro-1,3-dimethylbenzo[c]thien-5-yl)-
• CAS NO: 137601-57-1
• Molecular Formula: C16H19NS
• Molecular Weight: 257.4
• Mol File: 137601-57-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-(4,5,6,7-tetrahydro-1,3-dimethylbenzo[c]thien-5-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-(4,5,6,7-tetrahydro-1,3-dimethylbenzo[c]thien-5-yl)-(137601-57-1)
• EPA Substance Registry System: Benzenamine, 4-(4,5,6,7-tetrahydro-1,3-dimethylbenzo[c]thien-5-yl)-(137601-57-1)

Safety Data

• Hazardous Substances Data: 137601-57-1(Hazardous Substances Data)

Upstream product

• 1520-21-4 4-vinyl benzylamine 
• 137601-56-0 5,7-Dimethyl-1,4-dihydro-thieno[3,4-d]pyridazine 

Relevant articles and documents

Transition state structure and frontier orbital influence on the cycloaddition reactions of 2,5-dimethyl-3,4-dimethylenethiophene with styrenes and benzaldehydes

The biradical 2,5-dimethyl-3,4-dimethylenethiophene reacts with styrenes and benzaldehydes to give fused cycloadducts. The effect of substituents on the efficiency of the benzaldehyde trapping reaction resembles that of normal electron-demand Diels-Adler reactions and is linear with the Hammett σ-constant. With the styrenes, the Hammett plot is non-linear. Frontier orbital theory provides a rationalization of these effects in terms of the uniquely small HOMO-LUMO gap characteristic of biradicals.