137638-43-8

Basic information

• Product Name: diethyl (2-phenylpropanoyl)phosphonate
• Synonyms: diethyl (2-phenylpropanoyl)phosphonate
• CAS NO: 137638-43-8
• Molecular Weight: 270.265
• Mol File: 137638-43-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: diethyl (2-phenylpropanoyl)phosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl (2-phenylpropanoyl)phosphonate(137638-43-8)
• EPA Substance Registry System: diethyl (2-phenylpropanoyl)phosphonate(137638-43-8)

Safety Data

• Hazardous Substances Data: 137638-43-8(Hazardous Substances Data)

Upstream product

• 25145-43-1 2-phenylpropionyl chloride 
• 122-52-1 triethyl phosphite 
• 34713-70-7 2-Phenylpropanal 

Downstream Products

• 278800-61-6 diethyl (1-hydroxy-2-phenylpropyl)phosphonate 
• 1417328-73-4 diethyl ((1R,2R)-1-hydroxy-2-phenylpropyl)phosphonate 
• 137619-34-2 (1-Amino-2-phenyl-propyl)-phosphonic acid diethyl ester 
• 137619-54-6 (1-Amino-2-phenyl-propyl)-phosphonic acid 
• 137619-18-2 {1-[(Z)-Hydroxyimino]-2-phenyl-propyl}-phosphonic acid diethyl ester 

Relevant articles and documents

Diametric stereocontrol in dynamic catalytic reduction of racemic acyl phosphonates: Divergence from α-Keto ester congeners

An unexpected dichotomy was observed in the Ru-catalyzed asymmetric transfer hydrogenation of acyl phosphonates: reduction proceeded from the opposite face relative to that observed in the analogous reduction of α-keto esters. The first highly selective catalytic hydrogenation of acyl phosphonates was utilized in the dynamic kinetic resolution of α-aryl acyl phosphonates, providing β-stereogenic α-hydroxy phosphonic acid derivatives.

A convenient and mild procedure for the preparation of α-keto phosphonates of 1-hydroxyphosphonates under solvent-free conditions using microwave

The Reactions of 1-hydroxyphosphonates on the alumina-supported CrO3 are accelerated by microwave irradiation under solvent-free conditions to afford a high yielding synthesis of α-keto phosphonates.

ORGANIC PHOSPHORUS COMPOUNDS 97. SYNTHESIS AND PROPERTIES OF 1-AMINO-2-ARYL- AND 2-PYRIDYL-ETHYLPHOSPHONIC ACIDS AND DERIVATIVES

1-Amino-2-(o, m, and p-pyridyl)-ethylphosphonic acids, 5α, 5β and 5γ, have been prepared by alkylation of benzylideneaminomethylphosphonate, followed by hydrogenation and hydrolysis, whereas 1-amino-2-(o, m, and p-methoxyphenyl)-ethylphosphonic acids, 5i,