137648-47-6Relevant articles and documents
Halogen Bonding Helicates Encompassing Iodonium Cations
Vanderkooy, Alan,Gupta, Arvind Kumar,F?ldes, Tamás,Lindblad, Sofia,Orthaber, Andreas,Pápai, Imre,Erdélyi, Máté
, p. 9012 - 9016 (2019)
The first halonium-ion-based helices were designed and synthesized using oligo-aryl/pyridylene-ethynylene backbones that fold around reactive iodonium ions. Halogen bonding interactions stabilize the iodonium ions within the helices. Remarkably, the distance between two iodonium ions within a helix is shorter than the sum of their van der Waals radii. The helical conformations were characterized by X-ray crystallography in the solid state, by NMR spectroscopy in solution and corroborated by DFT calculations. The helical complexes possess potential synthetic utility, as demonstrated by their ability to induce iodocyclization of 4-penten-1-ol.
Reversible Multicomponent and Gate Triggered by Stoichiometric Chemical Pulses Commands the Self-Assembly and Actuation of Catalytic Machinery
Biswas, Pronay Kumar,Saha, Suchismita,Gaikwad, Sudhakar,Schmittel, Michael
supporting information, p. 7889 - 7897 (2020/05/25)
The present work demonstrates the operation of a reversible supramolecular gate, i.e., an ensemble of various components linked by chemical communication, which is triggered by stoichiometric chemical inputs and by obeying the AND truth table delivers a s
Synthesis of a carbon analogue of scytonemin
Mukai, Chisato,Arima, Katsuya,Hirata, Shuichi,Yasuda, Shigeo
, p. 273 - 277 (2015/04/22)
The synthesis of a carbon analogue of scytonemin was accomplished on the basis of molybdenum-mediated intramolecular double Pauson-Khand type reaction of bis(allenyne), followed by the double aldol condensation of the formed double Pauson-Khand type adduct.