137654-04-7Relevant academic research and scientific papers
The thorpe-ingold effect in the synthesis of tetrahydro-furans and pyrans by competitive cyclisation with phenylthio migration
McIntyre, Sara,Sansbury, Francis H.,Warren, Stuart
, p. 5409 - 5412 (2007/10/02)
In cyclisations of triols with two tethered hydroxyl nucleophiles (giving ethers by acid-catalysed phenylthio migration) a gem-dimethyl group in the carbon chain bearing one of the OH groups favours cyclisation of that chain whether the new ring is five-
