137655-35-7Relevant academic research and scientific papers
Enantioselective addition of (Z)- And (E)-alkenylzinc bromides to aldehydes: Asymmetric synthesis of sec-allylalcohols
Oppolzer, Wolfgang,Radinov, Rumen N.
, p. 5777 - 5780 (2007/10/02)
In situ prepared (Z)- and (E)-1-alkenylzinc bromides 5 were added to various aldehydes 1 in the presence of lithiated (+)-N-methylephedrine or (+)-2-(N,N-dimethylamino)-1,2-diphenylethanol to give sec. allyalcohols 7 in high optical purity with simple rec
