137655-40-4Relevant academic research and scientific papers
1,2-Stereoinduction in Radical Reactions: Stereoselective Synthesis of 2-Alkyl-3-hydroxybutanoates
Bulliard, Michel,Zehnder, Margareta,Giese, Bernd
, p. 1600 - 1607 (2007/10/02)
Radical addition to 2-cyclohexyl-5-methylidene-6-methyl-1,3-dioxan-4-one (2) affords stereoselectively 5,6-trans-products trans-3.The size of the radical has no influence on the selectivity.These trans-acetals are converted into threo-3-hydroxy-butanoates
