137675-64-0Relevant academic research and scientific papers
Sequential Vinylcyclopropylcarbene and Anionic Oxy-cope Rearrangements: An Expedient Synthesis of Nine-Membered Rings
Herndon, James W.,McMullen, Leonard A.,Daitch, Charles E.
, p. 4547 - 4550 (2007/10/02)
5-Alkenyl-2-methoxy-2-cyclopentenones, readily available from thermolysis of 2-alkenylcyclopropylcarbene-chromium complexes, can be converted to nine-membered rings by treatment with vinylcerium reagents and subsequent anionic oxy-Cope rearrangement.
