137675-90-2Relevant academic research and scientific papers
SYNTHESIS OF POLYFLUORO-SUBSTITUTED PYRYLIUM SALTS WITH AN ACTIVE CH GROUP FROM POLYFLUOROCHALCONES
Orlova, N. A.,Gerasimova, T. N.,Kudinova, M. A.,Tolmachev, A. I.
, p. 1135 - 1141 (2007/10/02)
It was shown that polyfluoro-substituted diarylpyrylium salts with an active CH group at position 2 of the pyrylium ring can be obtained by the reaction of chalcones p-XC6F4COCH=CHPh (where X = F, MeO) with acetoacetic ester or cyclohexanone in the presence of acids.The isomeric chalcone PhCOCH=CHC6H5 undergoes condensation under analogous conditions with the formation of cyclohexenone derivatives.
