137677-32-8

Basic information

• Product Name: 2-Methoxy-3,6,6-trimethyl-5-oxo-heptanoic acid dimethylamide
• Synonyms: 2-Methoxy-3,6,6-trimethyl-5-oxo-heptanoic acid dimethylamide
• CAS NO: 137677-32-8
• Molecular Weight: 243.346
• Mol File: 137677-32-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Methoxy-3,6,6-trimethyl-5-oxo-heptanoic acid dimethylamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Methoxy-3,6,6-trimethyl-5-oxo-heptanoic acid dimethylamide(137677-32-8)
• EPA Substance Registry System: 2-Methoxy-3,6,6-trimethyl-5-oxo-heptanoic acid dimethylamide(137677-32-8)

Safety Data

• Hazardous Substances Data: 137677-32-8(Hazardous Substances Data)

Upstream product

• 20971-19-1 (E)-2,2-dimethylhex-4-en-3-one 
• 4128-76-1 methoxy acetic acid dimethylamide 

Relevant articles and documents

syn-Selctive Michael Addition of Lithiated 2-Alkoxyacetates and -acetamides to α,β-Unsaturated Carbonyl Compounds

The lithium Z-enolates derived from 2-alkoxyacetates and -acetamides undergo unusual syn-selective Michael addition to α,β-unsaturated carbonyl compounds, where the syn selectivity of the amide enolates is much higher than that of the ester enolates.Factors that influence the stereoselectivity are also discussed.