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tert-Butyl-((3R,5R)-5-isopropenyl-2,3-dimethyl-cyclohex-1-enyloxy)-dimethyl-silane is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 137679-03-9 Structure
  • Basic information

    1. Product Name: tert-Butyl-((3R,5R)-5-isopropenyl-2,3-dimethyl-cyclohex-1-enyloxy)-dimethyl-silane
    2. Synonyms:
    3. CAS NO:137679-03-9
    4. Molecular Formula:
    5. Molecular Weight: 280.526
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 137679-03-9.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: tert-Butyl-((3R,5R)-5-isopropenyl-2,3-dimethyl-cyclohex-1-enyloxy)-dimethyl-silane(CAS DataBase Reference)
    10. NIST Chemistry Reference: tert-Butyl-((3R,5R)-5-isopropenyl-2,3-dimethyl-cyclohex-1-enyloxy)-dimethyl-silane(137679-03-9)
    11. EPA Substance Registry System: tert-Butyl-((3R,5R)-5-isopropenyl-2,3-dimethyl-cyclohex-1-enyloxy)-dimethyl-silane(137679-03-9)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 137679-03-9(Hazardous Substances Data)

137679-03-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 137679-03-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,7,6,7 and 9 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 137679-03:
(8*1)+(7*3)+(6*7)+(5*6)+(4*7)+(3*9)+(2*0)+(1*3)=159
159 % 10 = 9
So 137679-03-9 is a valid CAS Registry Number.

137679-03-9Downstream Products

137679-03-9Relevant articles and documents

Samarium(II) iodide promoted radical ring opening reactions of cyclopropyl ketones

Batey,Motherwell

, p. 6211 - 6214 (1991)

Radical ring opening reactions of cyclopropyl ketones mediated by samarium(II) iodide-induced single electron transfer have permitted the elaboration of a tandem rearrangement cyclisation strategy. The resultant samarium enolates may be effectively quenched on oxygen or carbon by electrophiles.

SAMARIUM(II) IODIDE PROMOTED RADICAL RING OPENING REACTIONS OF CYCLOPROPYL KETONES

Batey, Robert A.,Motherwell, William B.

, p. 6649 - 6652 (2007/10/02)

Radical ring opening reactions of cyclopropyl ketones mediated by samarium(II) iodide-induced single electron transfer have permitted the elaboration of a tandem rearrangement cyclisation strategy.The resultant samarium enolates may be effectively quenched on oxygen or carbon by electrophiles.Key Words: Samarium(II) Iodide Reduction; Cyclopropylcarbinyl Radical Rearrangement; Cyclopropyl Ketone; Radical Cyclisation; Samarium Enolate.

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