137737-01-0Relevant articles and documents
The reactivity of Pd(PtBu3)2 towards the oxonium ion. Crystal structure of trans-tBu3P)2Pd(H)(CH3CN)>BPh4
Sommovigo, Milena,Pasquali, Marco,Leoni, Piero,Sabatino, Piera,Braga, Dario
, p. 119 - 126 (1991)
The reaction of Pd(PtBu3)2 with the strong acids H3O+X-, (X = BF3OH, BF4), gives the thermally unstable hydrides trans-tBu3P)2Pd(H)(H2O)>X.The thermally stable hydrides trans-tBu3P)2Pd(H)(CH3CN)>X were obtained by substitution of the water molecule by CH3CN.The reaction of the aquo-hydrides with CO, yielding tBu3)>2 and the crystal structure of trans-tBu3P)2Pd(H)(CH3CN)>BPh4 are also reported.