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1377382-40-5

[κ3-P,N,P-NH((CH2)2NHPiPr2)2Pd(C6H4F)]Cl is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1377382-40-5 Structure

  • Basic information

    1. Product Name: [κ3-P,N,P-NH((CH2)2NHPiPr2)2Pd(C6H4F)]Cl
    2. Synonyms:
    3. CAS NO:1377382-40-5
    4. Molecular Formula:
    5. Molecular Weight: 572.422
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1377382-40-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [κ3-P,N,P-NH((CH2)2NHPiPr2)2Pd(C6H4F)]Cl(CAS DataBase Reference)
    10. NIST Chemistry Reference: [κ3-P,N,P-NH((CH2)2NHPiPr2)2Pd(C6H4F)]Cl(1377382-40-5)
    11. EPA Substance Registry System: [κ3-P,N,P-NH((CH2)2NHPiPr2)2Pd(C6H4F)]Cl(1377382-40-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1377382-40-5(Hazardous Substances Data)

1377382-40-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1377382-40-5 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,7,7,3,8 and 2 respectively; the second part has 2 digits, 4 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1377382-40:
(9*1)+(8*3)+(7*7)+(6*7)+(5*3)+(4*8)+(3*2)+(2*4)+(1*0)=185
185 % 10 = 5
So 1377382-40-5 is a valid CAS Registry Number.

1377382-40-5Downstream Products

1377382-40-5Relevant articles and documents

Ni(II), Pd(II) and Pt(II) complexes of PNP and PSP tridentate amino-phosphine ligands

Sgro, Michael J.,Stephan, Douglas W.

, p. 6791 - 6802 (2012/07/02)

The ligands D((CH2)2NHPiPr2)2 (D = NH 1, S 2) react with (dme)NiCl2 or (PhCN)2MCl 2 (M = Pd, Pt) to give complexes of the form [D((CH2) 2NHPiPr2)2MX]X (X = Cl, I; M = Ni, Pd, Pt) which were converted to corresponding iodide derivatives by reaction with Me3SiI. Reaction of 1 or 2 with (COD)PdMeCl affords facile routes to [κ3P,N,P-NH((CH2)2NHPiPr 2)2PdMe]Cl (8a) and [κ3P,S,P-S((CH 2)2NHPiPr2)2PdMe]Cl (9a) in high yields. An alternative synthetic approach involves oxidative addition of MeI to a M(0) precursor yielding [κ3P,N,P-HN(CH2CH 2NHPiPr2)2NiMe]I (10), [κ3P,N, P-HN(CH2CH2NHPiPr2)2MMe]I (M = Pd 8b Pt 11) and [κ3P,S,P-S(CH2CH2NHPiPr 2)2MMe]I (M = Pd 9b, Pt 12). Alternatively, use of NEt3HCl in place of MeI produces the species [κ3P,N, P-HN(CH2CH2NHPiPr2)2MH]X (X = Cl, M = Ni 13a, Pd 14a, Pt 16a). The analogs containing 2; [κ3P,S,P- S((CH2)2NHPiPr2)2MH]X (M = Pd, X = PF615: M = Pt, X = Br, 17a, PF617b) were also prepared in yields ranging from 74-93%. In addition, aryl halide oxidative addition was also employed to prepare [κ3P,N,P-HN(CH2CH 2NHPiPr2)2MC6H4F]Cl (M = Ni 18, Pd 19) and [κ3P,S,P-S((CH2) 2NHPiPr2)2Pd(C6H4F)]Cl (20). Crystal structures of 3a, 4a, 5a, 6a, 8a, 9a, 14b and 16b are reported.

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