137769-30-3

Basic information

• Product Name: (S)-(+)-(diphenylphosphino)-2`-isopropoxy-1,1`-binaphthyl
• Synonyms: (S)-(+)-(diphenylphosphino)-2`-isopropoxy-1,1`-binaphthyl;(S)-(+)-(Diphenylphosphino)-2
• CAS NO: 137769-30-3
• Molecular Formula: C₃₅H₂₉OP
• Molecular Weight: 469.58
• Product Categories: Chiral Reagents
• Mol File: 137769-30-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 600.403 °C at 760 mmHg
• Flash Point: 398.814 °C
• Appearance: /
• CAS DataBase Reference: (S)-(+)-(diphenylphosphino)-2`-isopropoxy-1,1`-binaphthyl(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(+)-(diphenylphosphino)-2`-isopropoxy-1,1`-binaphthyl(137769-30-3)
• EPA Substance Registry System: (S)-(+)-(diphenylphosphino)-2`-isopropoxy-1,1`-binaphthyl(137769-30-3)

Safety Data

• Hazardous Substances Data: 137769-30-3(Hazardous Substances Data)

Usage

General Description

(S)-(+)-(diphenylphosphino)-2`-isopropoxy-1,1`-binaphthyl is a chiral ligand commonly used in asymmetric catalysis. (S)-(+)-(diphenylphosphino)-2`-isopropoxy-1,1`-binaphthyl is a phosphine derivative that consists of a binaphthyl backbone with an isopropoxy group and a diphenylphosphino group attached to it. The chiral nature of the compound arises from the asymmetry in the binaphthyl backbone, which makes it an effective ligand for promoting enantioselective reactions. It has been employed in a variety of catalytic processes, including asymmetric hydrogenation, allylic substitution, and transfer hydrogenation reactions. The unique structure and properties of this chemical make it a valuable tool for synthesizing complex molecules with high levels of enantiomeric purity.

Upstream product

• 602-09-5 1,1'-bi-2-naphthol 
• 4559-70-0 Diphenylphosphine oxide 
• 141807-44-5 (+/-)-2,2'-bis(trifluoromethanesulfonyloxy)-1,1-binaphthyl 
• 132532-04-8 (R)-2-diphenylphosphinyl-2'-trifluoromethanesulfonyloxy-1,1'-binaphthalene 
• 132548-91-5 (S)-(+)-2-hydroxy-2'-diphenylphosphinoyl-1,1'-binaphthyl 
• 137769-27-8 (S)-(-)-2-(diphenylphosphinyl)-2'-isopropoxy-1,1'-binaphthyl 

Relevant articles and documents

Synthesis of Optically Active 2-(Diarylphosphino)-1,1'-binaphthyls, Efficient Chiral Monodentate Phosphine Ligands

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Catalytic Asymmetric Synthesis of Optically Active 2-Alkanols via Hydrosilylation of 1-Alkenes with a Chiral Monophosphine-Palladium Catalyst

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