137777-11-8 Usage
Classification
methyl ester
Structural components
pyrrole ring, carboxylic acid, hydroxyphenyl group
Usage
organic synthesis, potential applications in pharmaceuticals and materials science
Safety precautions
potential hazards, should be handled and used with proper safety measures.
Check Digit Verification of cas no
The CAS Registry Mumber 137777-11-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,7,7,7 and 7 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 137777-11:
(8*1)+(7*3)+(6*7)+(5*7)+(4*7)+(3*7)+(2*1)+(1*1)=158
158 % 10 = 8
So 137777-11-8 is a valid CAS Registry Number.
137777-11-8Relevant articles and documents
Rearrangements of Pyrrole and Indole Substituted Enol Esters of Cyclohexane-1,3-dione
Oliver, James E.,Lusby, William R.,Waters, Rolland M.
, p. 1565 - 1568 (2007/10/02)
Enol esters 3a and 3b, from cyclohexane-1,3-dione and pyrrole-2-carbonyl chloride and indole-2-carbonyl chloride, respectively, rearranged in the presence of triethylamine to the enamino acids 7 and 12.In the presence of cyanide, 3b, also underwent the expected rearrangement to 4b, whereas only 7 was formed from 3a.Treatment of 7 with mercuric acetate in hot acetic acid resulted in decarboxylation and aromatization to phenol 9.