137789-05-0Relevant academic research and scientific papers
Enantioselektive Katalysen LX. Addition von optisch aktiven Aminen an P-substituierte Olefine
Brunner, Henri,Limmer, Stephan
, p. 173 - 180 (2007/10/02)
The addition of the optically active amines (-)-1-phenylethylamine, (+)-1-phenylethylamine, and (+)-3-aminomethylpinane to diphenylvinylphosphine oxide or 1,1-bis(diphenylphosphino)ethene sulfide gives new PN compounds which were used as cocatalysts in the cross coupling of 1-phenylethyl Grignard with vinylbromide and in the hydrosilylation of acetophenone with diphenylsilane.
