Cas 137789-18-5,(R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1R,2S,4aR,8aR)-2,4a-dimethyl-5-methylene-decahydro-naphthalen-1-yl ester

137789-18-5

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Basic information

Product Name: (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1R,2S,4aR,8aR)-2,4a-dimethyl-5-methylene-decahydro-naphthalen-1-yl ester
Synonyms:
CAS NO:137789-18-5
Molecular Formula:
Molecular Weight: 410.477
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1R,2S,4aR,8aR)-2,4a-dimethyl-5-methylene-decahydro-naphthalen-1-yl ester(CAS DataBase Reference)
NIST Chemistry Reference: (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1R,2S,4aR,8aR)-2,4a-dimethyl-5-methylene-decahydro-naphthalen-1-yl ester(137789-18-5)
EPA Substance Registry System: (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1R,2S,4aR,8aR)-2,4a-dimethyl-5-methylene-decahydro-naphthalen-1-yl ester(137789-18-5)

Safety Data

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Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 137789-18-5(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 137789-18-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,7,7,8 and 9 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 137789-18:
(8*1)+(7*3)+(6*7)+(5*7)+(4*8)+(3*9)+(2*1)+(1*8)=175
175 % 10 = 5
So 137789-18-5 is a valid CAS Registry Number.

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137789-18-5Relevant academic research and scientific papers

USE OF THE ME3Sn FUNCTION AS A READILY REMOVABLE "ANCHORING" GROUP IN THE SYNTHESIS OF ENANTIOMERICALLY PURE BICYCLIC ALCOHOLS AND KETONES

Piers, Edward,Roberge, Jacques Y.

, p. 5219 - 5222 (2007/10/02)

Subjection of (5R,6R)-(-)-3,6-dimethyl-5-trimethylstannyl-2-cyclohexen-1-one (11) to appropriate annulation sequences provides the cis-fused ketones 15, 20, and 21, which, upon reduction (Li, NH3, THF, t-BuOH) are converted smoothly into the enantiomerically pre bicyclic alcohols 16, 22, and 23, respectively.Compound 16 is readily transformed into the unichiral ketones 6 and 7.

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