137819-66-0

Basic information

• Product Name: (2S)-BORNANE-10,2-SULTAM GLYCINATE
• Synonyms: (2S)-BORNANE-10,2-SULTAM GLYCINATE
• CAS NO: 137819-66-0
• Molecular Formula: C₁₅H₂₄N₂O₃S₃
• Molecular Weight: 376.56
• Mol File: 137819-66-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (2S)-BORNANE-10,2-SULTAM GLYCINATE(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-BORNANE-10,2-SULTAM GLYCINATE(137819-66-0)
• EPA Substance Registry System: (2S)-BORNANE-10,2-SULTAM GLYCINATE(137819-66-0)

Safety Data

• Hazardous Substances Data: 137819-66-0(Hazardous Substances Data)

Usage

General Description

(2S)-BORNANE-10,2-SULTAM GLYCINATE is a chemical compound that is derived from the naturally occurring camphor molecule. It has a unique structure and is widely used in pharmaceuticals and chemical research. (2S)-BORNANE-10,2-SULTAM GLYCINATE has been shown to have antimicrobial and anti-inflammatory properties, making it suitable for use in medical and healthcare applications. Additionally, (2S)-BORNANE-10,2-SULTAM GLYCINATE has been studied for its potential as a chiral building block in organic synthesis, allowing for the creation of complex molecules with specific three-dimensional structures. Overall, this chemical shows promise for various applications in the fields of medicine, research, and material science.

Upstream product

• 58091-08-0 methyl N-(bis(methyl)thiomethilene)glycinate 
• 108448-77-7 (+)-camphorsultam 
• 332041-85-7 [3aR-[(3aS*,4S*,6aR*),3aα,6α,7aβ]]-3H-3a,6-methano-2,1-benzisothiazole, hexahydro-8,8-dimethyl-4-[[tetrahydro-1,3-dioxolo-5-(phenylmethyl)-2-oxo-[4,5-c]-pyrrol-4-yl]carbonyl]-2,2-dioxide 
• 332041-84-6 [3aR-[(3aR*,4R*,6aS*),3aα,6α,7aβ]]-3H-3a,6-methano-2,1-benzisothiazole, hexahydro-8,8-dimethyl-4-[[tetrahydro-1,3-dioxolo-5-(phenylmethyl)-2-oxo-[4,5-c]-pyrrol-4-yl]carbonyl]-2,2-dioxide 
• 332041-80-2 [3aR-[1(2R*,3R*),3aα,6α,7aβ]]-3-pyrrolidine-carboxylic acid, 1-(phenylmethyl)-2-[(tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazol-1(4H)-yl)-carbonyl]-methyl ester, S,S-dioxide 
• 635678-42-1 (1R,2S,4S)-N-(2,3-dibromopropionyl)-bornane-2,10-sultam 
• 153440-80-3 ((R)-1-Benzyl-aziridin-2-yl)-((1R,5S,7S)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-methanone 
• 119944-89-7 (2S)-N-(acryloyl)bornane-10,2-sultam 

Downstream Products

• 137718-68-4 Carbonic acid (Z)-4-[[(R)-1-((1R,5S,7S)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]decane-4-carbonyl)-but-3-enyl]-(2,4,6-trimethyl-benzenesulfonyl)-amino]-but-2-enyl ester methyl ester 
• 137718-74-2 (3R,4aR,7aR)-3-((1R,5S,7S)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]decane-4-carbonyl)-7-methyl-2-(2,4,6-trimethyl-benzenesulfonyl)-octahydro-[2]pyrindin-6-one 
• 137718-69-5 (3R,4aR,7aR)-3-((1R,5S,7S)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]decane-4-carbonyl)-7-methylene-2-(2,4,6-trimethyl-benzenesulfonyl)-octahydro-[2]pyrindin-6-one 
• 137718-67-3 N-[(R)-1-((1R,5S,7S)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]decane-4-carbonyl)-but-3-enyl]-2,4,6-trimethyl-benzenesulfonamide 
• 108448-77-7 (+)-camphorsultam 

Relevant articles and documents

Stereocontrolled 1,3-dipolar cycloadditions using Oppolzer's camphor sultam as the chiral auxiliary for carbonyl stabilized azomethine ylides

Two complementary approaches to substituted pyrrolidines via stereocontrolled 1,3-dipolar cycloaddition reactions of chiral azomethine ylides are described. In one approach, chiral azomethine ylides were generated by thermolysis of aziridine carboxylate sultams and trapped with a variety of dipolarophiles to give good yields of the corresponding cycloadducts. In the second approach, chiral azomethine ylides were generated from glycyl sultams by 'imine tautomerization' and trapped with dipolarophiles to give good yields of the corresponding cycloadducts.