1378381-36-2Relevant academic research and scientific papers
Absolute configuration for 1, n-glycols: A nonempirical approach to long-range stereochemical determination
Li, Xiaoyong,Burrell, Carmin E.,Staples, Richard J.,Borhan, Babak
, p. 9026 - 9029 (2012/07/13)
The absolute configurations of 1,n-glycols (n = 2-12, 16) bearing two chiral centers were rapidly determined via exciton-coupled circular dichroism (ECCD) using a tris(pentafluorophenyl)porphyrin (TPFP porphyrin) tweezer system in a nonempirical fashion devoid of chemical derivatization. A unique "side-on" approach of the porphyrin tweezer relative to the diol guest molecule is suggested as the mode of complexation.
