1378429-94-7

Basic information

• Product Name: 1-(3-(4-tert-butylcyclohexylidene)prop-1-ynyl)-4-methoxybenzene
• Synonyms: 1-(3-(4-tert-butylcyclohexylidene)prop-1-ynyl)-4-methoxybenzene
• CAS NO: 1378429-94-7
• Molecular Weight: 282.426
• Mol File: 1378429-94-7.mol

Chemical Properties

• CAS DataBase Reference: 1-(3-(4-tert-butylcyclohexylidene)prop-1-ynyl)-4-methoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(3-(4-tert-butylcyclohexylidene)prop-1-ynyl)-4-methoxybenzene(1378429-94-7)
• EPA Substance Registry System: 1-(3-(4-tert-butylcyclohexylidene)prop-1-ynyl)-4-methoxybenzene(1378429-94-7)

Safety Data

• Hazardous Substances Data: 1378429-94-7(Hazardous Substances Data)

Upstream product

• 104761-33-3 1-(iodomethylidene)-4-tert-butyl-cyclohexane 
• 768-60-5 4-methoxyphenylacetylen 

Relevant articles and documents

Microwave-assisted copper-catalyzed cross-coupling reaction of alkynes with aryl iodides and vinyl halides

The microwave-assisted, copper-catalyzed coupling of terminal alkynes with aryl iodides and vinyl halides is reported. In general, the reactions are completed in 10-30 min using 2-5 mol% [CuI(xantphos)] as a catalyst to provide the corresponding alkynes and enynes in good to excellent yields. A broad spectrum of aryl iodides, vinyl iodides, and bromides are coupled with aryl- and alkyl alkynes.

Copper-catalyzed coupling of alkynes with alkenyl halides

The synthesis of enynes from the coupling of terminal alkynes with alkenyl iodides and bromides is described. This system employs 1.0-5.0 mol% of CuI(Xantphos) as a catalyst. A variety of alkenyl iodides and bromides are coupled smoothly with terminal alkynes, affording enynes in good to excellent yields. Georg Thieme Verlag Stuttgart · New York.