1379012-37-9

Upstream product

• 1605-06-7 (-)-(2S,3S)-2,3-diphenylaziridine 
• 23190-16-1 (1R,2S)-2-Amino-1,2-diphenylethanol 
• 1379012-28-8 C₂₁H₂₁NS 

Downstream Products

• 1379012-69-7 2,4-dibromo-6-((E)-(((1S,2R)-1,2-diphenyl-2-((R)-p-tolylsulfinyl)ethyl)imino)methyl)phenol 
• 1379012-62-0 2,4-di-tert-butyl-6-((E)-(((1S,2R)-1,2-diphenyl-2-((R)-p-tolylsulfinyl)ethyl)imino)methyl)phenol 
• 1379012-68-6 2-((E)-(((1S,2R)-1,2-diphenyl-2-((R)-p-tolylsulfinyl)ethyl)imino)methyl)-4-fluorophenol 
• 1379012-59-5 2-((E)-(((1S,2R)-1,2-diphenyl-2-((R)-p-tolylsulfinyl)ethyl)imino)methyl)-4-methylphenol 
• 1379012-48-2 2-((E)-(((1S,2R)-1,2-diphenyl-2-((R)-p-tolylsulfinyl)ethyl)imino)methyl)phenol 
• 1379012-77-7 (1S,2R,E)-N-(2-methoxybenzylidene)-1,2-diphenyl-2-((R)-p-tolylsulfinyl)ethanamine 
• 1379012-58-4 4-chloro-2-((E)-(((1S,2R)-1,2-diphenyl-2-((R)-p-tolylsulfinyl)ethyl)imino)methyl)phenol 
• 1379012-66-4 4-bromo-2-((E)-(((1S,2R)-1,2-diphenyl-2-((R)-p-tolylsulfinyl)ethyl)imino)methyl)phenol 
• 1379012-61-9 2,4-dichloro-6-((E)-(((1S,2R)-1,2-diphenyl-2-((R)-p-tolylsulfinyl)ethyl)imino)methyl)phenol 
• 1570510-73-4 N-((1S,2R)-1,2-diphenyl-2-((R)-p-tolylsulfinyl)ethyl)benzamide 
• 1570510-59-6 N-((1S,2R)-1,2-diphenyl-2-((R)-p-tolylsulfinyl)ethyl)-2-(diphenylphosphino)benzamide 

Relevant academic research and scientific papers

Enantioselective synthesis of tetrahydrofuran derivatives by sequential henry reaction and iodocyclization of γ,δ-unsaturated alcohols

A sequential one-pot Cu-catalyzed asymmetric Henry reaction and iodocyclization is disclosed. The transformation provides efficient access to biologically and synthetically useful 2,2,5-trisubstituted tetrahydrofuran derivatives. The combination of Cu(OAc)2·H2O with a novel chiral sulfoxide-Schiff base hybrid ligand under mild reaction conditions tolerates a wide range of 4-substituted γ,δ-unsaturated aldehydes, and the subsequent iodocyclization furnishes the corresponding products in generally high yields with excellent enantioselectivities. The products can be easily converted into amines with excellent diastereo- and enantioselectivities.

Design of chiral sulfoxide-Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

A new class of chiral sulfoxide-Schiff base ligands has been developed by the rational combination of two privileged chiral backbones. These sulfoxide-Schiff base ligands were found to be highly efficient for Cu-catalyzed asymmetric Henry reactions (up to