137909-63-8Relevant academic research and scientific papers
Control of Diastereofacial Selectivity in the Nucleophilic Epoxidation of γ-Oxygenated-α,β-Unsaturated Sulphones
Jackson, Richard F. W.,Standen, Stephen P.,Clegg, William
, p. 5393 - 5396 (1991)
Epoxidation of γ-oxygenated-α,β-unsaturated sulphones 4-8 with lithium t-butyl hydroperoxide proceeds with moderate to high diastereoselectivity to give 2-phenylsulphonyl oxiranes 9-13.The sense of diastereoselectivity is dependent on the steric bulk of t
