137917-90-9

Upstream product

• 137917-89-6 6-hydroxy-5-nor-β-copaene 
• 1005-56-7 phenylcarbonochloridothioate 
• 124355-78-8 (1α,4β,5α,7R*)-(+/-)-7-chloro-4-isopropyl-1-methylbicyclo<3.1.1>heptan-6-one 
• 124508-22-1 (1α,4β,5α,7R*)-(+/-)-7-bromo-4-isopropyl-1-methylbicyclo<3.1.1>heptan-6-one 
• 137917-85-2 1-methyl-4(S*)-isopropyl-6(R*)-(2-propynyl)-7(R*)-bromobicyclo<3.1.1>heptan-6-ol 
• 137917-88-5 (1S,3aS,4R,7R,7aS)-7-Isopropyl-4-methyl-3-[1-trimethylsilanyl-meth-(E)-ylidene]-octahydro-1,4-cyclo-inden-1-ol 
• 137917-82-9 (1S,4R,5R,6S,7S)-7-Chloro-4-isopropyl-1-methyl-6-(3-trimethylsilanyl-prop-2-ynyl)-bicyclo[3.1.1]heptan-6-ol 
• 137917-84-1 (1S,4R,5R,6S,7S)-7-Bromo-4-isopropyl-1-methyl-6-(3-trimethylsilanyl-prop-2-ynyl)-bicyclo[3.1.1]heptan-6-ol 

Downstream Products

• 137917-91-0 5-nor-β-copaene 
• 137917-94-3 (1S,3aR,4R,7R,7aS)-7-Isopropyl-1-methoxy-4-methyl-3-methylene-octahydro-1,4-cyclo-indene 
• 137917-93-2 ((1S,3aR,4R,7R,7aS)-7-Isopropyl-4-methyl-3-methylene-octahydro-1,4-cyclo-inden-1-yloxy)-methanethiol 
• 137917-92-1 (1S,3aR,4R,7R,7aS)-7-Isopropyl-4-methyl-3-methylene-1-phenoxymethoxy-octahydro-1,4-cyclo-indene 

Relevant academic research and scientific papers

Total syntheses of (±)-α- And (±)-β-copaene and formal total syntheses of (±)-sativene, (±)-cis-sativenediol, and (±)-helminthosporal

Conversion of the previously reported, carvacrol-based 4(S*)-isopropyl-7(R*)-chlorobicyclo[3.1.1]heptan-6-one and its bromo equivalent into (±)-α- and (±)-β-copaene it described. Model 5-nor-β-copaene was synthesized in the following manner, (a) γ-(trimet