137958-27-1

Basic information

• Product Name: Ethanone, 1-(4,5-dimethyl-1,4-cyclohexadien-1-yl)- (9CI)
• Synonyms: Ethanone, 1-(4,5-dimethyl-1,4-cyclohexadien-1-yl)- (9CI)
• CAS NO: 137958-27-1
• Molecular Formula: C₁₀H₁₄O
• Molecular Weight: 150.21756
• Product Categories: ACETYLGROUP
• Mol File: 137958-27-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-(4,5-dimethyl-1,4-cyclohexadien-1-yl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(4,5-dimethyl-1,4-cyclohexadien-1-yl)- (9CI)(137958-27-1)
• EPA Substance Registry System: Ethanone, 1-(4,5-dimethyl-1,4-cyclohexadien-1-yl)- (9CI)(137958-27-1)

Safety Data

• Hazardous Substances Data: 137958-27-1(Hazardous Substances Data)

Upstream product

• 137958-20-4 1-((1S,6R)-6-Benzenesulfonyl-3,4-dimethyl-cyclohex-3-enyl)-ethanone 
• 1119-19-3 but-2-ynal 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 

Downstream Products

• 3637-01-2 3,4-dimethylacetophenone 

Relevant articles and documents

β-Phenylsulfonylenones as α,β-acetylenic ketones equivalents in Diels-Alder reactions

(E)-β-phenylsulfonylenones, readily prepared by oxidation of the alcohols, react with a wide variety of dienes in the presence of activated silica gel. The basic elimination of the phenylsulfonyl group in the resulting adducts gives high yields of the corresponding enones, thus showing the usefulness of these dienophiles as reactive synthetic equivalents of α,β-acetylenic ketones.