1379615-75-4Relevant articles and documents
Rhodium-catalyzed and zinc(II)-triflate-promoted asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones
Calvin, Joel R.,Frederick, Michael O.,Laird, Dana L. T.,Remacle, Jacob R.,May, Scott A.
supporting information; experimental part, p. 1038 - 1041 (2012/04/10)
The asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones has been accomplished using an in situ formed rhodium-Josiphos catalyst. The reaction is enhanced by addition of catalytic zinc(II) triflate, which significantly improves turnover fr