1379657-28-9Relevant academic research and scientific papers
Oxytrifluoromethylation of multiple bonds using copper catalyst under mild conditions
Egami, Hiromichi,Shimizu, Ryo,Sodeoka, Mikiko
supporting information, p. 5503 - 5506 (2012/11/07)
Oxytrifluoromethylation reaction of styrene derivatives and alkynes with external and internal oxygen nucleophiles, catalyzed by copper (I) salts under mild conditions, was developed. Direct formation of a β- trifluoromethylstyrene derivative from a styrene derivative was also achieved by the reaction in the presence of a Bronsted acid. Further transformation of the oxytrifluoromethylated products was conducted to demonstrate their utility. 2012 Elsevier Ltd. All rights reserved.
Electrophilic trifluoromethylation by copper-catalyzed addition of CF 3-transfer reagents to alkenes and alkynes
Janson, Paer G.,Ghoneim, Ibrahim,Ilchenko, Nadia O.,Szabo, Kalman J.
supporting information; experimental part, p. 2882 - 2885 (2012/07/14)
Regio- and stereoselective Cu-catalyzed addition of the above hypervalent iodine reagent to alkynes and alkenes was achieved. In the presence of CuI, the reaction is suitable to perform trifluoromethyl-benzoyloxylation and trifluoromethyl-halogenation of
