1379681-45-4Relevant academic research and scientific papers
Automated solid phase synthesis of oligoarabinofuranosides
Kandasamy, Jeyakumar,Hurevich, Mattan,Seeberger, Peter H.
, p. 4453 - 4455 (2013/06/26)
Automated solid phase synthesis enables rapid access to the linear and branched arabinofuranoside oligosaccharides. A simple purification step is sufficient to provide the conjugation ready oligosaccharides in good yield.
A practical silicon-free strategy for differentiation of hydroxy groups in arabinofuranose derivatives
Abronina, Polina I.,Podvalnyy, Nikita M.,Sedinkin, Sergey L.,Fedina, Ksenia G.,Zinin, Alexander I.,Chizhov, Alexander O.,Torgov, Vladimir I.,Kononov, Leonid O.
experimental part, p. 1219 - 1225 (2012/05/20)
Effective differentiation of 3,5-diol system and 2-hydroxy group in arabinofuranose derivatives, which is required for the preparation of building blocks useful for the synthesis of nucleoside analogues and oligosaccharide fragments of mycobacterial arabinogalactan and lipoarabinomannan, was achieved by using 3,5-di-O-benzoyl-1,2-O-benzylidene-βD-arabinofuranose or 3-O-(chloroacetyl)-β- d-arabinofuranose 1,2,5-orthobenzoate, both readily accessible from inexpensive methylα-d-arabinofuranoside via the corresponding glycosyl bromides. The use of expensive organosilicon protecting groups is completely avoided in this novel strategy, a feature that makes it amenable to scale-up. Georg Thieme Verlag Stuttgart New York.
