1379682-48-0Relevant academic research and scientific papers
Evidence of nanotubular self-organization in solution and solid states of heterochiral cyclo 1:1 [/-N α-Bn-hydrazino]mers series
Moussodia, Ralph-Olivier,Acherar, Samir,Romero, Eugénie,Didierjean, Claude,Jamart-Grégoire, Brigitte
, p. 3022 - 3029 (2015)
The cyclization of heterochiral 1:1 [α/α-Nα-Bn-hydrazino]mers leads to the corresponding cyclotetramer and cyclohexamer 3 and 4. X-ray crystallographic analysis of 3 unveils its ability to self-assemble into nanotubular structures. Further expe
An expedient and short synthesis of chiral α-hydrazinoesters: Synthesis and conformational analysis of 1:1 [α/α-N α-hydrazino]mers
Moussodia, Ralph-Olivier,Acherar, Samir,Bordessa, Andrea,Vanderesse, Régis,Jamart-Grégoire, Brigitte
, p. 4682 - 4692 (2012/07/28)
Different α-hydrazinoesters with high optical purity have been obtained in large scale via an SN2 protocol. A coupling reaction with a natural amino acid leads to the corresponding dimers, which have been oligomerized in order to obtain the 1:1 [α/α-Nα- hydrazino]mer series. Conformational studies show that these mixed oligomers are self-organized in solution via a succession of γ-turn and hydrazinoturn whatever the absolute configuration of the chiral carbons.
