1379777-17-9Relevant articles and documents
Organotin-catalyzed highly regioselective thiocarbonylation of nonprotected carbohydrates and synthesis of deoxy carbohydrates in a minimum number of steps
Muramatsu, Wataru,Tanigawa, Satoko,Takemoto, Yuki,Yoshimatsu, Hirofumi,Onomura, Osamu
, p. 4850 - 4853 (2012)
Nonprotected carbohydrates: The catalytic regioselective thiocarbonylation of carbohydrates by using organotin dichloride under mild conditions was demonstrated. The reaction afforded various deoxy saccharides in high yields and excellent regioselectivity in a minimum number of steps. The regioselectivity of the thiocarbonylation is attributed to the intrinsic character of the carbohydrates based on the stereorelationship of their hydroxy groups (see scheme). Copyright