1379829-52-3Relevant academic research and scientific papers
Highly diastereoselective construction of fused carbocycles from cyclopropane-1,1-dicarboxylates and cyclic enol silyl ethers: Scope, Mechanism, and origin of diastereoselectivity
Qu, Jian-Ping,Liang, Yong,Xu, Hao,Sun, Xiu-Li,Yu, Zhi-Xiang,Tang, Yong
scheme or table, p. 2196 - 2201 (2012/04/10)
Cyclopropane rings true: By selecting the appropriate substituents on the ester and silyl groups, fused cyclopentane derivatives with multiple contiguous stereocenters can be synthesized with excellent diastereoselectivity through CuII/bisoxazoline-catalyzed intermolecular [3+2] cycloaddition reactions of cyclopropane-1,1-dicarboxylates and cyclic enol silyl ethers (see scheme). Copyright
