1379835-67-2Relevant academic research and scientific papers
Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates
Parsons, Andrew T.,Senecal, Todd D.,Buchwald, Stephen L.
, p. 2947 - 2950 (2012/05/05)
Exchanging BF3 by CF3: The title reaction proceeds under exceedingly mild reaction conditions and provides 2-arylvinyl- and 2-heteroarylvinyl-substituted substrates with E/Z selectivities of more than 95:5. Experimental observations suggest that the reaction does not proceed through a transmetalation of the RBF3K species to the iron catalyst. Copyright
