1380096-83-2

Upstream product

• 1380096-57-0 (+)-(1R,2E,S(S))-1-phenyl-2-(p-tolylsulfinyl)hept-2-en-1-yl 2,2,2-trichloroacetimidate 
• 445282-37-1 (+)-(E)-1-phenyl-2-(S^S)-(p-tolylsulfinyl)hept-2-en-1-(R)-ol 

Relevant academic research and scientific papers

Sulfinyl-Mediated Stereoselective Overman Rearrangements and Diels-Alder Cycloadditions

Sulfinyl trichloroacetamides are readily obtained in excellent yields through a highly stereoselective Overman rearrangement. Related bis-allylic substrates lead to amido 2-sulfinyl butadiene derivatives in excellent yields, with total chemo- and diastereoselectivity. These amido dienyl sulfoxides undergo highly selective Diels-Alder cycloadditions with N-phenylmaleimide with remarkable stereocontrol by the sulfoxide moiety.

Sulfinyl-mediated stereoselective overman rearrangements and Diels-Alder cycloadditions

The Overman rearrangement of allylic sulfinyl trichloroacetimidates affords sulfinyl trichloroacetamides with high stereoselectivity and excellent yields. Bis-allylic substrates lead to amido 2-sulfinyl butadiene derivatives in excellent yields, with tota